This question is really about matching a named law in soil fertility to the correct scientist, and the trap is that two other big names in soil science are sitting right there as distractors.
- Justus von Liebig (1840): Liebig's lasting contribution is the Law of the Minimum, the idea that plant growth is held back by whichever nutrient is scarcest, relative to what the plant needs. That is a different law from restitution.
- Hilgard (1888): This points to the same scientist as option 4, associated with soil genesis and alkali soil studies in America, not with the restitution concept.
- J.B. Boussingault (1802-1882): Boussingault, working in France in the same broad period as Liebig, is the scientist credited with stating that a crop's removal of nutrients from the soil must be restored to it, otherwise fertility keeps declining, which is exactly the Law of Restitution described in the question.
- E.W. Hilgard (1833-1916): Again this is the American soil scientist known for pioneering soil survey and pedology work, not restitution.
Since the question is describing the return-of-nutrients idea word for word, the answer has to be Boussingault.
Let's summarize:
- Liebig gave the Law of the Minimum.
- Both Hilgard options refer to the same soil scientist, known for soil genesis work.
- Boussingault is the one who framed the Law of Restitution.
So option 3, J.B. Boussingault, is correct.