Ionization energy, the energy to remove an electron from a gaseous atom,
is determined by these factors:
• Atomic Size: Smaller atoms exhibit higher ionization energy due to stronger nuclear attraction.
• Nuclear Charge: Increased nuclear charge strengthens the nucleus-electron attraction, elevating ionization energy.
• Electron Type: S-orbital electrons, being less shielded than p, d, or f electrons, are more challenging to remove.
For instance, elements within the same period typically show rising ionization energy with increased nuclear charge.
Consider the following compounds:
(i) CH₃CH₂Br
(ii) CH₃CH₂CH₂Br
(iii) CH₃CH₂CH₂CH₂Br
Arrange the compounds in the increasing order of their boiling points.
Assertion (A): The boiling points of alkyl halides decrease in the order: RI>RBr>RCl>RF.
Reason (R): The boiling points of alkyl chlorides, bromides and iodides are considerably higher than that of the hydrocarbon of comparable molecular mass.
Arrange the following compounds in increasing order of their boiling point: \[ \text{(CH}_3\text{)}_2\text{NH, CH}_3\text{CH}_2\text{NH}_2, \text{CH}_3\text{CH}_2\text{OH} \]