Step 1: Use tangents:
The vector points up and right. With the x-axis, $\tan\alpha = \frac{A_y}{A_x} = \frac32$, and with the y-axis, $\tan\beta = \frac{A_x}{A_y} = \frac23$.
Step 2: Convert to cosines:
If $\tan\alpha = \frac32$, the right triangle has sides $2$, $3$ and hypotenuse $\sqrt{13}$, so $\cos\alpha = \frac{2}{\sqrt{13}}$.
In the same way, $\cos\beta = \frac{3}{\sqrt{13}}$. This matches option B.
Final Answer:
The pair of angles is option (B).
\[ \boxed{\cos^{-1}\frac{2}{\sqrt{13}},\ \cos^{-1}\frac{3}{\sqrt{13}}} \]