Question:medium

The acid which has a peroxy linkage is

Updated On: May 5, 2026
  • sulphurous aci
  • pyrosulphuric aci
  • dithionic acid
  • Caro- acid
Show Solution

The Correct Option is D

Solution and Explanation

To determine which acid contains a peroxy linkage, we need to understand what a peroxy linkage is. A peroxy linkage is characterized by an -O-O- linkage within a molecule. This is a common structural feature in peroxy acids.

Let's analyze the given options:

  1. Sulphurous Acid (H2SO3): Sulphurous acid is commonly known for having a structure without the presence of a -O-O- bond. It consists of sulphur, oxygen, and hydrogen but lacks the peroxy linkage.
  2. Pyrosulphuric Acid (Oleum, H2S2O7): Pyrosulphuric acid, also known as oleum, contains two sulfur atoms and more oxygen atoms than sulphuric acid but does not contain a peroxy linkage.
  3. Dithionic Acid (H2S2O6): Dithionic acid is known to contain two sulphur atoms but does not incorporate an -O-O- bond.
  4. Caro- Acid (Peroxymonosulfuric Acid, H2SO5): Caro's acid, also known as peroxymonosulfuric acid, is the acid that contains a peroxy linkage. Its structure can be represented as H-O-O-S(=O)2-OH. Clearly, it has the -O-O- bond required for the peroxy linkage.

Therefore, the correct answer to the question "The acid which has a peroxy linkage is" is Caro- acid.

This thorough examination of the structural details of each option clearly explains why Caro- acid is the only choice with a peroxy linkage.

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