Step 1: Lay out the statements.
All Polymers are Cakes; Some Plastics are not Cakes; All Plastics are Synthetic Fibers.
Step 2: Use the definite some-not statement.
Because some Plastics are not Cakes, those particular Plastics exist and lie outside Cakes.
Step 3: Check Conclusion I.
Those non-Cake Plastics are still Synthetic Fibers, since all Plastics are, so there exist Synthetic Fibers that are not Cakes. Conclusion I follows.
Step 4: Check Conclusion III.
All Polymers are Cakes, but the Plastics that are not Cakes can never be Polymers, so the Polymer set and Plastic set cannot coincide; No Polymer is a Plastic follows.
Step 5: Check Conclusions II and IV.
Nothing links Cakes with Synthetic Fibers in general, and nothing links Polymers with Synthetic Fibers, so II and IV are not guaranteed.
Step 6: Select the option.
Only I and III follow.
\[ \boxed{\text{Only I and III follow.}} \]