Brownian motion comes from lopsided collisions, at any instant a colloidal particle gets hit slightly more from one side than the other by the fast moving molecules of the medium, and it jitters off in that direction.
Two things control how vigorous this jitter is. First, a smaller particle is easier to shove around, the same imbalance in collisions produces a bigger displacement on a light, small particle than on a heavy, bulky one.
Second, the medium itself has to let the particle move. A viscous medium resists motion and drags the particle back, damping the jitter, while a thin, low viscosity medium offers little resistance and lets the particle respond freely to every collision.
Combining both factors, the fastest Brownian movement needs a particle that is easy to push, that is small size, in a medium that does not resist that push, that is low viscosity.
So the correct choice is option (2).
Consider the following compounds:
(i) CH₃CH₂Br
(ii) CH₃CH₂CH₂Br
(iii) CH₃CH₂CH₂CH₂Br
Arrange the compounds in the increasing order of their boiling points.
Assertion (A): The boiling points of alkyl halides decrease in the order: RI>RBr>RCl>RF.
Reason (R): The boiling points of alkyl chlorides, bromides and iodides are considerably higher than that of the hydrocarbon of comparable molecular mass.
Arrange the following compounds in increasing order of their boiling point: \[ \text{(CH}_3\text{)}_2\text{NH, CH}_3\text{CH}_2\text{NH}_2, \text{CH}_3\text{CH}_2\text{OH} \]