Question:medium

Pure nitrogen is prepared in the laboratory by heating a mixture of

Updated On: Jun 24, 2026
  • $NH_4OH + NaCI$
  • $NH_4N0_3 + NaCI$
  • $NH_4CI + NaOH$
  • $NH_4CI + NaNO_2$
Show Solution

The Correct Option is D

Solution and Explanation

To prepare pure nitrogen gas in the laboratory, a common method involves the reaction of NH_4Cl (ammonium chloride) and NaNO_2 (sodium nitrite). The chemical equation for this reaction is:

NH_4Cl + NaNO_2 \rightarrow N_2(g) + 2H_2O + NaCl

Let's break down this reaction to understand why it produces pure nitrogen gas:

  1. Reactants: NH_4Cl and NaNO_2 are the reactants. When these two compounds are heated together, they undergo a decomposition reaction.
  2. Decomposition of Ammonium Nitrite: The mixture of NH_4Cl and NaNO_2 decomposes to form nitrogen gas, water, and sodium chloride. The nitrogen gas released is colorless and odorless.
  3. Products: The products of this reaction are nitrogen gas (N_2), water (H_2O), and sodium chloride (NaCl). Among these, only nitrogen is a gaseous product, making it easy to collect and purify.

The other options presented do not efficiently yield nitrogen gas:

  • NH_4OH + NaCl: This combination does not effectively produce nitrogen gas.
  • NH_4NO_3 + NaCl: This mixture also does not readily produce nitrogen gas upon heating.
  • NH_4Cl + NaOH: This combination typically produces ammonia gas and water, not nitrogen.

Therefore, the correct choice is NH_4Cl + NaNO_2 for preparing pure nitrogen gas in the laboratory.

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