Step 1: Understand the setup.
PQ is tangent to the circle at Q (point on the circle), O is the center, and OP = 2OQ. Let OQ = r (radius), so OP = 2r.
Step 2: Apply the tangent-radius perpendicularity.
Since PQ is a tangent at Q, OQ is perpendicular to PQ: $\angle OQP = 90^\circ$.
Step 3: Set up the right triangle.
In right triangle OQP: Hypotenuse = OP = 2r, one leg OQ = r.
Step 4: Use trigonometry to find angle OPQ.
\[ \sin(\angle OPQ) = \frac{OQ}{OP} = \frac{r}{2r} = \frac{1}{2} \]
Step 5: Solve for the angle.
\[ \angle OPQ = \sin^{-1}\left(\frac{1}{2}\right) = 30^\circ \]
Step 6: Conclusion.
The measure of $\angle OPQ$ is $30^\circ$.
\[ \boxed{30^\circ} \]