In this question, we need to determine which compound has phosphorus in the +3 oxidation state.
Let's analyze each option:
- Phosphorous acid (H3PO3): In this compound, hydrogen has a typical oxidation state of +1 and oxygen -2. Solving for the oxidation state of phosphorus:
3(+1) + P + 3(-2) = 0
3 + P - 6 = 0
P = +3
So, phosphorus in phosphorous acid is in the +3 oxidation state.
- Orthophosphoric acid (H3PO4): Similarly, using the same logic:
3(+1) + P + 4(-2) = 0
3 + P - 8 = 0
P = +5
Phosphorus in orthophosphoric acid is in the +5 oxidation state.
- Hypophosphorous acid (H3PO2): Similarly, solving for phosphorus:
3(+1) + P + 2(-2) = 0
3 + P - 4 = 0
P = +1
Phosphorus in hypophosphorous acid is in the +1 oxidation state.
- Metaphosphoric acid (HPO3): Solving for phosphorus:
1(+1) + P + 3(-2) = 0
1 + P - 6 = 0
P = +5
Phosphorus in metaphosphoric acid is in the +5 oxidation state.
From the above analysis, only Phosphorous acid (H3PO3) has phosphorus in the oxidation state of +3.
Therefore, the correct answer is Phosphorous acid.