
A linear relationship observed between log |R₀| and time indicates a first-order reaction.
In a first-order reaction, reactant concentration diminishes exponentially with time, adhering to the equation:
\[ \ln [R] = \ln [R_0] - kt \]
Taking the base-10 logarithm of both sides yields a linear equation, confirming that a plot of \(\log [R]\) against time will be a straight line.
For a first-order reaction, the slope of the \(\log [R]\) versus time graph corresponds to \(-k\), where \(k\) represents the rate constant.
Therefore, the slope \(m\) of the graph is given by:
\[ \text{slope} = -k \]