| List-I (System) | List-II (Axial lengths and angles) |
|---|---|
| (A) Cubic | (I) \(a = b = c, \alpha = \beta = \gamma = 90^\circ\) |
| (B) Tetragonal | (II) \(a = b \neq c, \alpha = \beta = \gamma = 90^\circ\) |
| (C) Orthorhombic | (III) \(a \neq b \neq c, \alpha = \beta = \gamma = 90^\circ\) |
| (D) Hexagonal | (IV) \(a = b \neq c, \alpha = \beta = 90^\circ, \gamma = 120^\circ\) |
Crystal systems are categorized by their axial dimensions and angles:
• Cubic: All axial lengths are equal, and all angles are 90°.
• Tetragonal: Two axial lengths are equal, one differs; all angles are 90°.
• Orthorhombic: All axial lengths are unequal; all angles are 90°.
• Hexagonal: Two axial lengths are equal, one differs; two angles are 90° and one is 120°.
Consequently, the accurate matching is: (A) - (I), (B) - (III), (C) - (II), (D) - (IV).
Consider the following compounds:
(i) CH₃CH₂Br
(ii) CH₃CH₂CH₂Br
(iii) CH₃CH₂CH₂CH₂Br
Arrange the compounds in the increasing order of their boiling points.
Assertion (A): The boiling points of alkyl halides decrease in the order: RI>RBr>RCl>RF.
Reason (R): The boiling points of alkyl chlorides, bromides and iodides are considerably higher than that of the hydrocarbon of comparable molecular mass.
Arrange the following compounds in increasing order of their boiling point: \[ \text{(CH}_3\text{)}_2\text{NH, CH}_3\text{CH}_2\text{NH}_2, \text{CH}_3\text{CH}_2\text{OH} \]