Step 1: Write out the vertex correspondence.
$\Delta ABC \sim \Delta EDF$ means $A\leftrightarrow E$, $B\leftrightarrow D$, $C\leftrightarrow F$, so the true angle equalities are $\angle A=\angle E$, $\angle B=\angle D$, $\angle C=\angle F$.
Step 2: Check each option against this map.
Options (A), (B) and (D) all use side ratios that follow this correspondence correctly, so they are true.
Step 3: Test option (C).
Option (C) claims $\angle A=\angle D$, but the map says $\angle A$ should equal $\angle E$, not $\angle D$, so this statement is false.
\[ \boxed{\text{Option (C)}} \]