Step 1: Write out the vertex correspondence as a table.
$\Delta ABC \sim \Delta EDF$ tells us $A \leftrightarrow E$, $B \leftrightarrow D$, $C \leftrightarrow F$.
Step 2: Read off the true angle equalities from the table.
This correspondence gives $\angle A = \angle E$, $\angle B = \angle D$, and $\angle C = \angle F$.
Step 3: Compare each option against the table.
Option (C) claims $\angle A = \angle D$, but the table shows $\angle A$ actually equals $\angle E$, not $\angle D$. The other three options (perimeter ratio, side ratio, and the combined ratio) all follow correctly from the table.
So option (C) is the one that is not true.
\[ \boxed{\text{Option (C)}} \]