Question:medium

In hydrogen atom, the de Broglie wavelength of an electron in the second Bohr orbit is : [Given that Bohr radius, $a_0$ = $52.9\, pm$ ]

Updated On: Jun 15, 2026
  • $211.6\, pm$
  • $211.6 \,\pi\, pm$
  • $52.9 \, \pi\, pm$
  • $105.8 \,pm$
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The Correct Option is B

Solution and Explanation

To determine the de Broglie wavelength of an electron in the second Bohr orbit of a hydrogen atom, we will follow these steps:

  1.  The de Broglie wavelength (\(\lambda\)) is given by the formula: \(\lambda = \frac{h}{p}\) , where:
    • \(h\) is Planck's constant.
    • \(p\) is the momentum of the electron.
  2. For an electron in the Bohr orbit, the momentum (\(p\)) can also be expressed as: \(p = \frac{mvr}{r} = mv\) , where:
    • \(m\) is the mass of the electron.
    • \(v\) is the velocity of the electron.
    • \(r\) is the radius of the orbit, specifically given as: \(r = n^2a_0\).
  3. For the second Bohr orbit (\(n = 2\)), the radius (\(r\)) is: \(r_2 = 2^2a_0 = 4a_0\).
  4. The de Broglie wavelength for the electron in the n-th orbit is: \(\lambda = \frac{h}{mv} = \frac{2\pi r}{n}\).
    • Substituting for \(r\) in the second orbit:
    • \(\lambda = \frac{2\pi \times 4a_0}{2} = 4\pi a_0\)
  5. Finally, substituting the given Bohr radius \(a_0 = 52.9 \, \text{pm}\):
    • \(\lambda = 4\pi \times 52.9 \, \text{pm} = 211.6\pi \, \text{pm}\)

The correct answer is \(211.6 \,\pi\, \text{pm}\), which matches the option: \(211.6 \,\pi\, \text{pm}\).

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