An alternative, purely geometric route is to notice that three vectors of the same magnitude \( F \) (the two original forces and their resultant) form an equilateral triangle when added tip-to-tail, and to check each angle option against that geometric picture.
Visualising the vector triangle formed by the two forces and their resultant shows that only one specific angle produces a resultant of equal length to the two original forces, forming an equilateral triangle.
So the correct answer is \( 120^\circ \).