Step 1: Start from Snell's law at the denser-to-rarer boundary.
For a ray going from a medium of refractive index \(n\) (denser) into air, \(n\sin\beta = \sin r\), where \(\beta\) is the incidence angle and \(r\) the refraction angle. Since \(n>1\), \(r\) is always larger than \(\beta\).
Step 2: Push the refracted ray to its limit.
As \(\beta\) increases, \(r\) increases faster and reaches its maximum possible value \(90^\circ\). The incidence angle at which this happens is defined as the critical angle \(\alpha\), so \(n\sin\alpha = \sin 90^\circ = 1\).
Step 3: Go beyond the limit.
If we make \(\beta\) even larger than \(\alpha\), the equation \(\sin r = n\sin\beta\) would demand \(\sin r > 1\), which is mathematically impossible. Nature responds by not transmitting the ray at all; instead it reflects the entire beam back inside the denser medium.
Step 4: Conclusion.
This complete reflection (total internal reflection) begins only once \(\beta\) exceeds \(\alpha\). Hence the required condition is that the incidence angle be greater than the critical angle.
\[\boxed{\beta > \alpha}\]