Step 1: Solve for y' in general:
From $y'(e^y + x) = -y$, $y' = -\frac{y}{e^y + x}$.
Step 2: Differentiate the quotient:
At $x = 0$, $y = 1$: $y' = -\frac{1}{e}$. Then $y'' = -\frac{y'(e^y + x) - y(e^y y' + 1)}{(e^y + x)^2}$.
In the numerator, $y'(e^y + x) = -\frac1e\cdot e = -1$ and $y(e^y y' + 1) = 1\cdot(e\cdot(-\frac1e) + 1) = 0$. So the numerator is $-1 - 0 = -1$, and $y'' = -\frac{-1}{e^2} = \frac{1}{e^2}$. Option (B).
Final Answer:
$\left(-\frac1e, \frac{1}{e^2}\right)$.
\[ \boxed{\left(-\frac{1}{e},\frac{1}{e^2}\right)} \]