To solve this question, we need to understand the concept of de Broglie wavelength and how it relates to the kinetic energy of particles.
The de Broglie wavelength is given by the formula:
\(\lambda = \frac{h}{p}\)
where:
The momentum \(p\) can also be expressed as:
\(p = \sqrt{2mK}\)
where:
Given that the de Broglie wavelength of the electron is equal to that of the proton, we have:
\(\lambda_e = \lambda_p\)
Substituting the expression for the de Broglie wavelength, we get:
\(\frac{h}{\sqrt{2m_e K_e}} = \frac{h}{\sqrt{2m_p K_p}}\)
Upon simplifying, this can be written as:
\(\sqrt{\frac{K_e}{m_e}} = \sqrt{\frac{K_p}{m_p}}\)
Squaring both sides gives:
\(\frac{K_e}{m_e} = \frac{K_p}{m_p}\)
Rearranging the terms, we have:
\(K_e = K_p \cdot \frac{m_e}{m_p}\)
Since the mass of the electron \(m_e\) is much less than the mass of the proton \(m_p\), the factor \(\frac{m_e}{m_p}\) is a very small number.
Therefore, for equal de Broglie wavelengths, the kinetic energy of the electron \(K_e\) must be greater than that of the proton \(K_p\) to compensate for its lower mass.
Thus, the correct answer is \(\large{KE_e > KE_p}\).
Given below are two statements:
Statement I: The conversion proceeds well in a less polar medium. \[ {CH}_3{CH}_2{CH}_2{CH}_2{Cl} \xrightarrow{{HO}^-} {CH}_3{CH}_2{CH}_2{CH}_2{OH} + {Cl}^- \] Statement II: The conversion proceeds well in a more polar medium. \[ {CH}_3{CH}_2{CH}_2{CH}_2{Cl} \xrightarrow{{R}_3{N}} {CH}_3{CH}_2{CH}_2{CH}_2{NH}_2 + {Cl}^- \] In the light of the above statements, choose the correct answer from the options given below: