To find the angle between vectors \( \mathbf{b} \) and \( \mathbf{c} \), we first need to determine the expression for \( \mathbf{c} \) given by \( \mathbf{c} = 2\mathbf{a} \times \mathbf{b} - 3\mathbf{b} \).
\(|\mathbf{c}| = \sqrt{|2\mathbf{a} \times \mathbf{b}|^2 + (-3|\mathbf{b}|)^2}\)
\(|\mathbf{a} \times \mathbf{b}| = |\mathbf{a}| |\mathbf{b}| \sin \theta\)
\(\cos \theta = \frac{\mathbf{a} \cdot \mathbf{b}}{|\mathbf{a}| |\mathbf{b}|} = \frac{2}{4} = \frac{1}{2}\)
\(|\mathbf{a} \times \mathbf{b}| = 4 \sin \frac{\pi}{3} = 4 \cdot \frac{\sqrt{3}}{2} = 2\sqrt{3}\)
\(|2\mathbf{a} \times \mathbf{b}| = 2 \cdot 2\sqrt{3} = 4\sqrt{3}\)
\(|\mathbf{c}| = \sqrt{(4\sqrt{3})^2 + (-3 \cdot 4)^2} = \sqrt{48 + 144} = \sqrt{192} = 8\sqrt{3}\)
\(\mathbf{b} \cdot \mathbf{c} = \mathbf{b} \cdot (2\mathbf{a} \times \mathbf{b} - 3\mathbf{b}) = -3 |\mathbf{b}|^2 = -3 \cdot 16 = -48\)
\(\cos \alpha = \frac{\mathbf{b} \cdot \mathbf{c}}{|\mathbf{b}| |\mathbf{c}|} = \frac{-48}{4 \times 8\sqrt{3}} = -\frac{1}{2}\)
This confirms that the angle between \( \mathbf{b} \) and \( \mathbf{c} \) is indeed \(\frac{5\pi}{6}\).