Step 1: Recall the name
Aspirin is 2-acetoxybenzoic acid, also called acetylsalicylic acid.
Step 2: Look for the groups
Look for a ring with a carboxylic acid and an ester (acetate) group in the ortho positions.
Step 3: Eliminate
Structures with a free phenolic -OH or with two ester groups on the ring are salicylic acid, methyl salicylate or dimethyl phthalate, not aspirin.
Final Answer:
The correct structure has -COOH and an acetoxy group next to each other on the ring.
\[ \boxed{\text{(C) }\text{Structure with ortho -COOH and -OCOCH}_{3}\text{ groups}} \]