Question:medium

Identify the major product from the following reaction sequence

Show Hint

The Hell-Volhard-Zelinsky reaction brominates the \(\alpha\)-carbon of carboxylic acids using: \[ Br_2/\text{Red }P \]
Updated On: Jun 25, 2026
  • 1
  • 2
  • 3
  • 4
Show Solution

The Correct Option is A

Solution and Explanation

Step 1: Identify the starting material.
From the solution context, the starting compound is a primary alcohol attached to a cyclopentane ring (cyclopentylmethanol type).
Step 2: PCC oxidation of primary alcohol.
PCC (pyridinium chlorochromate) is a mild selective oxidant. It converts a primary alcohol to an aldehyde and stops there: \[ R\text{-}CH_2OH \xrightarrow{PCC} R\text{-}CHO \]
Step 3: Product of PCC step.
The primary alcohol gives the corresponding aldehyde (e.g., cyclopentanecarbaldehyde).
Step 4: Tollens oxidation of the aldehyde.
Tollen's reagent \( [Ag(NH_3)_2]^+ \) is a mild oxidant that selectively oxidises aldehydes to carboxylic acids. Silver is reduced to metallic silver: \[ R\text{-}CHO + 2[Ag(NH_3)_2]^+ + 2OH^- \rightarrow R\text{-}COOH + 2Ag \downarrow + 4NH_3 + H_2O \]
Step 5: Identify the final product.
The aldehyde formed by PCC is further oxidised by Tollen's reagent to give the carboxylic acid.
Step 6: State the answer.
The major product is the carboxylic acid (option 1). \[ \boxed{\text{Carboxylic acid (option 1)}} \]
Was this answer helpful?
0