Question

Identify the incorrect statement.

• A. When \( \text{(–)–2-bromooctane} \) is reacted with aqueous KOH, the substitution follows \( S_N2 \) mechanism and product formed is \( \text{(–)} \)-Octan-2-ol.
• B. Benzylic halides show higher reactivity towards \( S_N1 \) reaction.
• C. The reaction of \( \text{C}_6\text{H}_5\text{CH}_2 \text{– CHCl} \) with alc. KOH on heating yields two products.
• D. Optically active \( \text{(–)} \)-2-Methylbutan-1-ol on reaction with HCl yields a product \( (+) \)-1-Chloro-2-methylbutane.

Hint:

In \( S_N2 \) reactions, the nucleophile attacks from the opposite side of the leaving group, leading to inversion of configuration. In \( S_N1 \) reactions, the carbocation formed is planar, allowing for a mix of products with retention or inversion of configuration.

Answer 1

The Correct Option is A