Question:medium

Identify the geometry of $\text{TeF}_4$ molecule from the following.

Show Hint

Molecules with 5 electron pairs ($AB_4L$ type) always follow the trigonal bipyramidal parent geometry.
Updated On: May 14, 2026
  • Linear
  • Tetrahedral
  • Trigonal bipyramidal
  • Trigonal
Show Solution

The Correct Option is C

Solution and Explanation

Step 1: Understanding the Concept:
The structural geometry of a molecule can be accurately predicted using Valence Shell Electron Pair Repulsion (VSEPR) theory by counting the number of bonding electron pairs and non-bonding lone pairs around the central atom.
Step 2: Key Formula or Approach:
Approach: Apply VSEPR theory by determining the number of valence electrons on the central atom, calculating the steric number (bonding domains + lone pairs), and identifying the corresponding electron geometry.
Step 3: Detailed Explanation:
1. Determine valence electrons: The central atom is Tellurium ($\text{Te}$), which belongs to Group 16 of the periodic table (same as Oxygen and Sulfur). Therefore, it possesses 6 valence electrons. 2. Calculate bonding and lone pairs: $\text{Te}$ forms 4 single covalent bonds with 4 Fluorine ($\text{F}$) atoms. - Number of bonding pairs (bp) = 4. - Electrons utilized in bonding = 4. - Remaining valence electrons = $6 - 4 = 2$ electrons, which constitutes exactly 1 lone pair (lp). 3. Determine steric number and hybridization: Steric number (total electron domains) = bp + lp = $4 + 1 = 5$. A steric number of 5 directly corresponds to $sp^3d$ hybridization. 4. Identify the geometry: The base {electron-pair geometry} for 5 domains is trigonal bipyramidal. Due to the presence of one lone pair occupying an equatorial position to minimize repulsion, the actual physical {molecular shape} is "see-saw". Because "see-saw" is not among the provided options, the question is utilizing the term "geometry" to refer to the fundamental electron-pair geometry that dictates the overall spatial structure, which is trigonal bipyramidal.
Step 4: Final Answer:
The parent electron-pair geometry of $\text{TeF}_4$ is trigonal bipyramidal.
Was this answer helpful?
0