Question:medium

Identify correct decreasing order of basic strength of amines

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Aliphatic amines are stronger bases than ammonia, which is stronger than aniline.
Updated On: Oct 1, 2026
  • \(\text{CH}_3\text{NH}_2 > (\text{CH}_3)_2\text{NH} > \text{C}_6\text{H}_5\text{NH}_2 > \text{NH}_3\)
  • \((\text{CH}_3)_2\text{NH} > \text{CH}_3\text{NH}_2 > \text{NH}_3 > \text{C}_6\text{H}_5\text{NH}_2\)
  • \(\text{NH}_3 > \text{CH}_3\text{NH}_2 > (\text{CH}_3)_2\text{NH} > \text{C}_6\text{H}_5\text{NH}_2\)
  • \(\text{C}_6\text{H}_5\text{NH}_2 > (\text{CH}_3)_2\text{NH} > \text{CH}_3\text{NH}_2 > \text{NH}_3\)
Show Solution

The Correct Option is B

Solution and Explanation

Step 1: Compare the substituents on N
Two CH$_3$ groups, one CH$_3$, none, and one phenyl.

Step 2: Rank
More electron donation means a stronger base, and phenyl withdraws electron density by resonance. This gives the order in option (B).

Final Answer:
Option (B) lists the correct decreasing basic strength. \[ \boxed{(\text{CH}_3)_2\text{NH} > \text{CH}_3\text{NH}_2 > \text{NH}_3 > \text{C}_6\text{H}_5\text{NH}_2} \]
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