A primary amine is an organic compound characterized by the \( -NH_2 \) functional group, formed when one hydrogen atom in ammonia is substituted by an alkyl or aryl group. Of the provided choices, \( \text{Ethylamine} \) (structure \( \text{CH}_3\text{CH}_2\text{NH}_2 \)) possesses the \( -NH_2 \) group, identifying it as a primary amine. Conversely, \( \text{Diethylamine} \) and \( \text{Triethylamine} \) are classified as secondary and tertiary amines, respectively. \( \text{Aniline} \) also features an aromatic \( -NH_2 \) group.