Step 1: Components:
Take $\vec P$ along the x-axis. With the angle $\theta$ between them, $\vec Q=(Q\cos\theta,\,Q\sin\theta)$. The condition $PQ\cos\theta=PQ\sin\theta$ gives $\theta=45^{\circ}$.
Step 2: Add and Square:
$\vec R=(P+Q/\sqrt2,\ Q/\sqrt2)$. $R^2=P^2+\sqrt2PQ+\dfrac{Q^2}2+\dfrac{Q^2}2=P^2+Q^2+\sqrt2PQ$.
Step 3: Answer:
$R=\sqrt{P^2+Q^2+\sqrt2PQ}$. Option (D).
Final Answer:
Option (D).
\[ \boxed{\text{(D) } \sqrt{P^2+Q^2+\sqrt{2}\,PQ}} \]