Question:medium

For a first order reaction, A(g) $\rightarrow$ B(g) at 35 $^\circ$C, the volume of "A" left in the reaction vessel at various times are given below. [Given data: $\log(5/4) = 0.0969$]
What is the value of rate constant?

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For first-order reactions, the half-life is independent of the initial concentration/volume. You can check $k$ at different intervals ($t=20, 30$) to verify consistency.
Updated On: May 1, 2026
  • $0.02231 \text{ min}^{-1}$
  • $0.04231 \text{ min}^{-1}$
  • $0.06231 \text{ min}^{-1}$
  • $0.08231 \text{ min}^{-1}$
  • $0.1231 \text{ min}^{-1}$
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The Correct Option is A

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