Question:easy

Find the pH of a solution formed by mixing equal volume of solution of \(0.1\) M sodium propionate and \(0.1\) molar propionic acid.
(Given The dissociation constant of propionic acid is \(1.3\times 10^{-5}\))

Show Hint

Equal volumes of equal concentrations give salt/acid ratio of 1, so pH = pKa.
Updated On: Oct 1, 2026
  • \(2.45\)
  • \(4.89\)
  • \(5.98\)
  • \(6.89\)
Show Solution

The Correct Option is B

Solution and Explanation

Step 1: Plan:
Treat it as the equilibrium $\text{CH}_3\text{CH}_2\text{COOH} \rightleftharpoons \text{H}^+ + \text{CH}_3\text{CH}_2\text{COO}^-$ with the salt supplying the common ion.

Step 2: Use the equilibrium expression:
\[ [\text{H}^+] = K_a\frac{[\text{acid}]}{[\text{salt}]} \]
The two solutions have the same molarity and the same volume, so the ratio of acid to salt is $1$. Therefore $[\text{H}^+] = K_a = 1.3\times10^{-5}$ M.

Step 3: Convert to pH:
\[ \text{pH} = -\log(1.3\times10^{-5}) = 4.89 \]
A value of $2.45$ would need a strong acid. Values near $6$ to $7$ would mean little acid is left, which is not the case here.

Final Answer:
The pH is $4.89$, so option (B) is correct. \[ \boxed{4.89} \]
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