Question:medium

Find A

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\(\mathrm{MnO_2}\) selectively oxidizes allylic and benzylic alcohols to carbonyls.
Updated On: Jun 19, 2026
  • (a)
  • (b)
  • (c)
  • (d)
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The Correct Option is B

Solution and Explanation

The question involves using the reagent \(\text{MnO}_2\)to oxidize a compound, resulting in compound A. Let's solve and understand the reaction step-by-step:

  1. In the given compound, we have a benzene ring with a hydroxyl group \((\text{-OH})\)directly attached to it as a primary alcohol.
  2. \(\text{MnO}_2\)is a selective oxidizing agent that primarily oxidizes allylic and benzylic alcohols to the corresponding carbonyl compounds.
  3. The primary alcohol on the benzene ring, being a benzylic alcohol, will be oxidized by \(\text{MnO}_2\)to form the corresponding aldehyde.
  4. Thus, the product formed, compound A, will have a carbonyl group \((\text{-CHO})\)instead of the hydroxyl group \((\text{-OH})\)on the benzene ring, leading to the formation of benzaldehyde.

Upon examining the options, the correct structure of compound A corresponds to option (b), which is benzaldehyde:

  • (b) Benzaldehyde, which has a formyl group \((\text{-CHO})\)attached to the benzene ring.
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