Given enthalpy of combustion of carbon:
C(s) + O2(g) -> CO2(g)}, (Delta)H = -393.5 kJ mol^-1
This means formation of 1 mol (44 g) of CO₂ releases 393.5 kJ of heat.
Step 1: Moles of CO₂ in 35.2 g
CO2 = 44g mol}^{-1} = 35.2 44 g mol^-1 = 0.8 mol
Step 2: Heat released for 0.8 mol CO₂
(Delta) H = 0.8 (-393.5) kJ = -314.8 kJ
The heat released upon formation of 35.2 g of CO₂ from carbon and dioxygen is: \[ \boxed{q \approx -3.15 \times 10^{2}\ \text{kJ} \; \text{(i.e. } -314.8\ \text{kJ)}} \]