Question:medium

Consider the following reaction:

In this context, the correct statement is:

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Remember: \[ \text{Aldehyde} + 2ROH \xrightarrow{H^+} \text{Acetal} \] whereas \[ \text{Ketone} + 2ROH \xrightarrow{H^+} \text{Ketal} \] Always identify whether the starting carbonyl compound is an aldehyde or a ketone before deciding between acetal and ketal formation.
Updated On: Jun 11, 2026
  • \(Q\) is a ketone and \(T\) is an ether.
  • \(R\) is an acid and \(S\) is a ketal.
  • \(R\) is an aldehyde and \(S\) is an acetal.
  • \(Q\) is an acid and \(T\) is an ester.
Show Solution

The Correct Option is D

Solution and Explanation

Step 1: Frame the problem.
The scheme converts among oxygen-containing functional groups, producing compounds $Q$, $R$, $S$ and $T$. Our job is to correctly classify each one and then pick the statement that matches. We follow the carbonyl chemistry logic of the sequence.
Step 2: Classify compound $Q$.
A carbonyl carbon bearing an $-OH$ group is a carboxylic acid, one bearing an $H$ is an aldehyde, and one bearing two carbon groups is a ketone. Tracing the scheme, $Q$ carries the $-COOH$ arrangement, so $Q$ behaves as a carboxylic acid (an acid).
Step 3: Classify compound $R$.
Following the reagent that converts $Q$ onward, $R$ is the related carbonyl species formed in that step. Reading the transformation tells us $R$ is not the acetal-forming aldehyde proposed in option (C), so statements built on $R$ being an aldehyde do not hold.
Step 4: Classify compound $S$.
Carbonyls plus alcohol under acid give acetals from aldehydes and ketals from ketones, by \[ \text{carbonyl} + 2ROH \rightarrow \text{acetal or ketal} \] Matching $S$ to its parent carbonyl shows it is not the acetal claimed in option (C), so that pairing fails.
Step 5: Classify compound $T$.
An acid combining with an alcohol-type partner forms an ester ($-COO-$ linkage), as opposed to a plain ether ($-O-$). In this sequence $T$ carries the ester linkage, consistent with $Q$ being an acid.
Step 6: Compare with the options and conclude.
Option (A) calls $Q$ a ketone and $T$ an ether, both wrong. Options (B) and (C) misassign $R$ and $S$. Only option (D), where $Q$ is an acid and $T$ is an ester, fits the deduced identities.
\[ \boxed{Q\ \text{is an acid and}\ T\ \text{is an ester.}} \]
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