The Carnot engine, a theoretical thermodynamic cycle, achieves maximum possible efficiency through its reversibility. Its reversibility is proven by the Second Law of Thermodynamics, which governs entropy changes and the direction of thermodynamic processes. According to the Second Law, an isolated system's total entropy remains constant (∆S = 0) in reversible processes, but increases (∆S>0) in irreversible ones.
Comprising reversible steps, the Carnot cycle can operate in reverse, resulting in a zero net entropy change for the entire cycle. The proof demonstrates that no other engine operating between the same two temperatures can surpass the Carnot engine's efficiency without violating the Second Law. This relies on the principle that reversible processes leave no net trace and that a more efficient engine would contradict the Second Law.
Consider the following compounds:
(i) CH₃CH₂Br
(ii) CH₃CH₂CH₂Br
(iii) CH₃CH₂CH₂CH₂Br
Arrange the compounds in the increasing order of their boiling points.
Assertion (A): The boiling points of alkyl halides decrease in the order: RI>RBr>RCl>RF.
Reason (R): The boiling points of alkyl chlorides, bromides and iodides are considerably higher than that of the hydrocarbon of comparable molecular mass.
Arrange the following compounds in increasing order of their boiling point: \[ \text{(CH}_3\text{)}_2\text{NH, CH}_3\text{CH}_2\text{NH}_2, \text{CH}_3\text{CH}_2\text{OH} \]