Step 1: Plan:
Work out $nR$ first, then divide.
Step 2: Steps:
$nR = 2\times0.0821 = 0.1642$ L atm K$^{-1}$. $PV = 24.6\times5.0 = 123$ L atm.
$T = \frac{123}{0.1642} \approx 749$ K, and $749 - 273 = 476^{\circ}$C.
Final Answer:
The temperature is about $476^{\circ}$C, option (A).
\[ \boxed{476^{\circ}\text{C}} \]