Question:easy

Calculate the boiling point of an aqueous solution containing 18 g glucose in 100 g water if the molal elevation constant of water is \(0.5 \text{K kg mol}^{-1}\).
[Molar mass of glucose \(= 180 \text{g mol}^{-1}\) and boiling point of water \(= 100 ^{\circ}\text{C}\)]

Show Hint

Delta Tb = Kb times molality; add to 100 C.
Updated On: Oct 1, 2026
  • \(100 ^{\circ}\text{C}\)
  • \(100.5 ^{\circ}\text{C}\)
  • \(101.0 ^{\circ}\text{C}\)
  • \(101.5 ^{\circ}\text{C}\)
Show Solution

The Correct Option is B

Solution and Explanation

Step 1: Molality:
$m = \dfrac{18/180}{100/1000} = \dfrac{0.1}{0.1} = 1$ mol/kg.

Step 2: Elevation:
$\Delta T_b = 0.5\times1 = 0.5$ K.

Step 3: Final boiling point:
$T_b = 100 + 0.5 = 100.5\ ^{\circ}$C, option (B). Glucose does not ionise, so no van't Hoff factor is needed.

Final Answer:
The boiling point is 100.5 C. \[ \boxed{\text{(B) }100.5\ ^{\circ}\text{C}} \]
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