Question:medium

Benzene diazonium chloride on reaction with phenol in weakly basic medium gives

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Benzene diazonium chloride is a weak electrophile and undergoes an azo coupling reaction with electron rich aromatic compounds such as phenol.
Updated On: Jun 16, 2026
  • Azobenzene
  • Benzene
  • Chlorobenzene
  • p-hydroxyazobenzene
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The Correct Option is D

Solution and Explanation

Step 1: Nature of the diazonium salt.
Benzene diazonium chloride is a weak electrophile and reacts with electron rich aromatic rings in a coupling reaction.

Step 2: Role of phenol and the basic medium.
Phenol is electron rich. In weakly basic medium part of it changes to the even more reactive phenoxide ion.

Step 3: The coupling.
The diazonium ion attacks the phenol ring at the para position (which is most reactive and least crowded). This is azo coupling.

Step 4: The product.
A \(-N=N-\) bridge joins the two rings, giving p-hydroxyazobenzene, an orange dye.

Step 5: Conclusion.
The product of the reaction is p-hydroxyazobenzene.

Answer: p-hydroxyazobenzene.
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