Step 1: Soil colloids carry negative surface charge, so Assertion (A) about cations determining aggregation needs a charge-based explanation.
Step 2: Adsorbed cations like \( \text{Ca}^{2+} \) bridge two negatively charged particles at once, pulling them together into flocs.
Step 3: This bridging is exactly the mechanism behind aggregate formation, so Reason (R) explains Assertion (A) directly.
Step 4: Correct option, both (A) and (R) are correct and (R) is the correct explanation of (A).