Question:medium

Acetylation of a secondary amine in alkaline medium yields

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Secondary amines give tertiary amides on acetylation.
Updated On: Jun 16, 2026
  • N,N-dialkyl acetamide
  • N,N-dialkyl amine
  • N,N-dialkyl amide
  • acetyl dialkyl amine
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The Correct Option is A

Solution and Explanation

The acetylation of a secondary amine in an alkaline medium results in the formation of an N,N-dialkyl acetamide. Let's go through the steps involved in this reaction to understand why this is the correct answer.

  1. Definition of Acetylation: Acetylation is a reaction in which an acetyl group (\(CH_3CO\)) is introduced into a molecule. In the case of amines, acetylation involves the substitution of a hydrogen atom on the nitrogen atom with an acetyl group.
  2. Structure of a Secondary Amine: A secondary amine is characterized by having two alkyl or aryl groups attached to a nitrogen atom, along with one hydrogen atom.
  3. Reaction Mechanism:
    • When a secondary amine undergoes acetylation, the hydrogen atom attached to the nitrogen is replaced by an acetyl group.
    • The reaction generally occurs in the presence of an acetylating agent like acetic anhydride or acetyl chloride under alkaline conditions.
    • The alkaline medium ensures that the amine remains nucleophilic, allowing it to attack the acetyl group effectively.
  4. Formation of N,N-Dialkyl Acetamide: The product of this reaction is an N,N-dialkyl acetamide, where both the alkyl groups from the original secondary amine, and the newly introduced acetyl group, are attached to the nitrogen atom.

To justify the selection of the correct answer from the options:

  • Correct Answer: N,N-dialkyl acetamide. This reflects the product formed after the acetylation of a secondary amine, as explained above.
  • Other Options:
    • N,N-dialkyl amine: This is the initial structure of a secondary amine before acetylation.
    • N,N-dialkyl amide: This term is nonspecific in this context, as 'amide' without the prefix 'acetyl-' does not describe the acetamide formed.
    • Acetyl dialkyl amine: This is not a commonly recognized nomenclature for the reaction product.

The correct answer, therefore, is N,N-dialkyl acetamide, as it accurately represents the result of the acetylation process in an alkaline medium.

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