Step 1: Use energy conservation in the gravitational field.
At launch the projectile has kinetic energy plus gravitational potential energy at the surface, and at the top it is momentarily at rest with only potential energy. So \[ \frac12 mV^2-\frac{GMm}{R}=-\frac{GMm}{R+h} \]
Step 2: Bring in the escape speed.
Escape speed satisfies $V_E^2=\dfrac{2GM}{R}$, and the launch speed is $V=\alpha V_E$, so $V^2=\alpha^2 V_E^2=\alpha^2\dfrac{2GM}{R}$.
Step 3: Substitute into the energy equation.
The kinetic term becomes $\dfrac12 m\,\alpha^2\dfrac{2GM}{R}=\alpha^2\dfrac{GMm}{R}$, so $\alpha^2\dfrac{GMm}{R}-\dfrac{GMm}{R}=-\dfrac{GMm}{R+h}$.
Step 4: Cancel and simplify.
Dividing through by $GMm$, $\dfrac{\alpha^2-1}{R}=-\dfrac{1}{R+h}$, which rearranges to $\alpha^2=1-\dfrac{R}{R+h}=\dfrac{h}{R+h}$.
Step 5: Put in the numbers.
With $h=800$ km and $R=6400$ km, \[ \alpha^2=\frac{800}{6400+800}=\frac{800}{7200}=\frac19 \]
Step 6: Take the root and conclude.
So $\alpha=\dfrac13$.
\[ \boxed{\dfrac13} \]