Question

A mixture of alkyl halide and aryl halide with sodium in dry ether. What is the name of reaction?

• A. Fittig reaction
• B. Finkelstein reaction
• C. Wurtz-Fittig reaction
• D. Wurtz reaction

Hint:

Remember these three related name reactions easily: alkyl + alkyl gives Wurtz reaction, aryl + aryl gives Fittig reaction, and alkyl + aryl gives Wurtz-Fittig reaction.

Answer 1

The Correct Option is C

Step 1: Understanding the Concept:
Coupling reactions using Sodium metal are named based on the types of halides being joined together.
Step 2: Formula Application:
1. Wurtz Reaction: Two alkyl halides ($R-X + R-X$). 2. Fittig Reaction: Two aryl halides ($Ar-X + Ar-X$). 3. Wurtz-Fittig Reaction: One alkyl and one aryl halide ($R-X + Ar-X$).
Step 3: Explanation:
The reaction involves the coupling of an alkyl group and an aryl group to form an alkyl-substituted aromatic compound (like Toluene). $R-X + 2Na + X-Ar \xrightarrow{\text{dry ether}} R-Ar + 2NaX$.
Step 4: Final Answer:
The reaction is the Wurtz-Fittig reaction.