Step 1: The set up.
A hollow metal sphere of radius $r$ carries some charge $Q$. Outside the sphere it behaves as if all the charge sat at the centre. The potential difference between the surface (distance $r$) and a point at distance $3r$ is $V$. We want the electric field at distance $3r$.
Step 2: Potential and field formulas.
Outside the sphere, at distance $x$,
\[ V_x = \frac{kQ}{x}, \qquad E_x = \frac{kQ}{x^2} \]
Step 3: Write the two potentials.
\[ V_{\text{surface}} = \frac{kQ}{r}, \qquad V_{\text{outer}} = \frac{kQ}{3r} \]
Step 4: Use the given difference.
\[ V = \frac{kQ}{r} - \frac{kQ}{3r} = \frac{kQ}{r}\left(1 - \frac{1}{3}\right) = \frac{2kQ}{3r} \]
Solve for the charge term:
\[ kQ = \frac{3rV}{2} \]
Step 5: Field at distance 3r.
\[ E = \frac{kQ}{(3r)^2} = \frac{kQ}{9r^2} \]
Step 6: Substitute and simplify.
\[ E = \frac{3rV/2}{9r^2} = \frac{3rV}{18r^2} = \frac{V}{6r} \]
This is option (4).
\[ \boxed{E = \frac{V}{6r}} \]