Step 1: State the given condition.
When the reflected and refracted rays are perpendicular to each other, the angle between them is $90^\circ$.
Step 2: Use geometry to relate the angles.
Let $i$ be the angle of incidence and $r$ be the angle of refraction. The reflected ray makes angle $i$ with the normal on the same side.
The angle between the reflected ray and the refracted ray is $(90^\circ - i) + (90^\circ - r) = 180^\circ - i - r$. Wait - more simply: reflected ray is on the same side as incident, making angle $i$ with the normal. Refracted ray makes angle $r$ on the other side. The angle between reflected and refracted rays is $180^\circ - i - r$. Setting this to $90^\circ$ gives:
\[
i + r = 90^\circ \implies r = 90^\circ - i
\]
Step 3: Apply Snell's law at the air-glass interface.
\[
n_1 \sin i = n_2 \sin r
\]
With $n_1 = 1$ (air) and $n_2 = 1.4$ (glass):
\[
\sin i = 1.4 \sin(90^\circ - i) = 1.4 \cos i
\]
Step 4: Divide both sides by $\cos i$.
\[
\frac{\sin i}{\cos i} = 1.4 \implies \tan i = 1.4
\]
Step 5: Solve for the angle of incidence.
\[
i = \tan^{-1}(1.4)
\]
Step 6: State the answer.
This angle is known as Brewster's angle. At this angle, the reflected light is completely polarised.
\[
\boxed{\tan^{-1}(1.4)}
\]