Question:hard

\(200\) mL of ethylene gas and \(150\) mL of HCl gas were allowed to react at \(1\) bar. Pressure to form gaseous ethyl chloride. What is the work done during the reaction?

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Find the volume consumed: the net volume change is minus 150 mL, so w = -P delta V is positive.
Updated On: Oct 1, 2026
  • \(15\) J
  • \(30\) J
  • \(150\) J
  • \(300\) J
Show Solution

The Correct Option is A

Solution and Explanation

Step 1: Use the pressure-volume unit shortcut:
1 bar $\times$ 1 mL = $10^5$ Pa $\times 10^{-6}$ m$^3$ = 0.1 J.

Step 2: Find the net contraction:
HCl is the limiting reagent, so 150 mL each of $\text{C}_2\text{H}_4$ and HCl turn into 150 mL of $\text{C}_2\text{H}_5\text{Cl}$. The mixture shrinks by 300 - 150 = 150 mL.

Step 3: Compute the work:
Because the system is compressed, work is done on the system and is positive: $w = 150 \times 0.1 = 15$ J.

Step 4: Check the sign:
Gas volume decreased, so the surroundings do work on the system, so $w > 0$. The magnitude 15 J matches option A.

Final Answer:
Using 0.1 J per mL at 1 bar, the 150 mL contraction gives 15 J. \[ \boxed{\text{(A) }15\ \text{J}} \]
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