Step 1: Open out both sides.
Use the sum and difference formulas on $2\sin(\theta + \tfrac{\pi}{3}) = \cos(\theta - \tfrac{\pi}{6})$.
With $\cos\tfrac{\pi}{3} = \tfrac12$, $\sin\tfrac{\pi}{3} = \tfrac{\sqrt3}{2}$, $\cos\tfrac{\pi}{6} = \tfrac{\sqrt3}{2}$, $\sin\tfrac{\pi}{6} = \tfrac12$.
Step 2: Write the expanded equation.
$$\sin\theta + \sqrt3\cos\theta = \tfrac{\sqrt3}{2}\cos\theta + \tfrac12\sin\theta$$
Step 3: Gather like terms.
$$\tfrac12\sin\theta = -\tfrac{\sqrt3}{2}\cos\theta \Rightarrow \sin\theta = -\sqrt3\cos\theta$$
Dividing by $\cos\theta$ gives $\tan\theta = -\sqrt3$.
\[ \boxed{-\sqrt3} \]