Each of these four sections governs a different, specific aspect of negotiable instruments, so the quickest approach is matching topic to number.
The correct answer is Section 87.
A helpful way to sort these four sections is by asking exactly which stage of an instrument's life each one governs, creation and change, payment, or currency terms.
Since the question asks about material alteration and its effects generally, not the narrower payment-protection scenario, the correct provision is Section 87.