Step 1: Abscisic acid and ethylene are hormones that interact with GA signalling but do not block its synthesis.
Step 2: Benzothiadiazole activates disease resistance, unrelated to GA biosynthesis.
Step 3: Prohexadione-calcium inhibits the late-stage dioxygenase enzymes of GA biosynthesis, like paclobutrazol and trinexapac-ethyl.
Step 4: The correct answer is Prohexadione-calcium.