Question:medium

Which of the following reactions is an example of Clemmensen reduction?

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There are two main named reactions to reduce a carbonyl group (aldehyde/ketone) completely to an alkane (-CH$_2$-): 1. Clemmensen Reduction: Uses Zn-Hg and conc. HCl. It is performed in acidic conditions and is not suitable for acid-sensitive compounds. 2. Wolff-Kishner Reduction: Uses NH$_2$NH$_2$ and a strong base (KOH). It is performed in basic conditions and is not suitable for base-sensitive compounds.
Updated On: Mar 30, 2026
  • R-CO-Cl + H$_2 \xrightarrow{Pd/BaSO_4}$ R-CHO + HCl
  • R-CHO $\xrightarrow{(i)NH_2NH_2, (ii)KOH/Glycol}$ R-CH$_3$
  • R-CO-OC$_2$H$_5 \xrightarrow{1. DIBAL-H, 2. H_2O}$ R-CHO + C$_2$H$_5$OH
  • R-CO-CH$_3 \xrightarrow{Zn-Hg/HCl}$ R-CH$_2$-CH$_3$
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The Correct Option is D

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