Step 1: Understand the question.
We must choose the process that gives a pure metal from an impure one. Some choices only treat the ore, not the final metal.
Step 2: Look at calcination.
Calcination heats a carbonate ore in little air to give the oxide. It treats the ore, not the impure metal. So it is not the answer.
Step 3: Look at roasting.
Roasting heats a sulphide ore in plenty of air to give the oxide. Again this is an ore step, not a purifying step for the metal.
Step 4: Look at smelting.
Smelting reduces the oxide to crude metal using heat and a reducing agent. It gives impure metal, not pure metal.
Step 5: Look at electrolytic refining.
Here the impure metal is the anode and a thin pure sheet is the cathode. On passing current, pure metal moves onto the cathode and the impurities fall away. This gives a very pure metal.
Step 6: Choose the right process.
Only electrolytic refining turns an impure metal into a pure metal.
Step 7: State the final answer.
The process for getting pure metal is:
\[ \boxed{\text{Electrolytic Refining}} \]