Step 1: State the invertibility test.
A square matrix is invertible exactly when its determinant is non-zero; a zero determinant means it is singular.
Step 2: Test A.
$|A|=\begin{vmatrix}2&3\\10&15\end{vmatrix}=2\cdot15-3\cdot10=30-30=0$, so A is not invertible.
Step 3: Test B.
In B the first row $(1,2,3)$ equals the third row $(1,2,3)$. Two identical rows force the determinant to be 0, so B is not invertible.
Step 4: Test C.
In C, row1 + row2 $=(1+3,2+4,3+5)=(4,6,8)$, which is row3. The rows are dependent, so $|C|=0$ and C is not invertible.
Step 5: Test D.
Expand along the first row: $|D|=2\begin{vmatrix}1&0\\4&5\end{vmatrix}-4\begin{vmatrix}1&0\\1&5\end{vmatrix}+2\begin{vmatrix}1&1\\1&4\end{vmatrix}=2(5)-4(5)+2(3)=10-20+6=-4$.
Step 6: Conclude.
Only D has a non-zero determinant ($-4$), so only D is invertible, matching option (4).
\[ \boxed{\text{only } D} \]