Step 1: Recall the standard forms
The three standard adiabatic forms are $PV^{\gamma}$, $TV^{\gamma-1}$ and $P^{1-\gamma}T^{\gamma}$, each equal to a constant.
Step 2: Compare the options
Options (A), (B) and (C) match these forms exactly.
Step 3: Why option D fails
The pressure exponent has the wrong sign. With $P^{\gamma-1}$ and $T^{\gamma-1}$ both positive, the relation would need $PT$ to stay constant, which is not true in an adiabatic change.
Final Answer:
Only option (D) is not one of the standard adiabatic relations.
\[ \boxed{\text{(D) }P^{\gamma -1}T^{\gamma -1}=\text{constant}} \]