Step 1: Understanding the Question:
We need to evaluate the hardness of the given water sample in terms of CaCO3 equivalent.
Step 2: Key Formula or Approach:
Convert MgCl2 into CaCO3 equivalent and calculate the concentration in ppm.
Step 3: Detailed Explanation:
The water contains 19 mg of MgCl2 in 2 kg. The equivalent CaCO3 mass is \(19\times100/95=20\) mg. Hence, hardness equals \(20/2=10\) mg/kg, which is numerically equal to 10 ppm.
Step 4: Final Answer:
The hardness value is 10 ppm.